In order to improve the electrochemical cycle stability of the re–mg–ni-based a2 b7-type electrode alloys, a small amount of si has been added into the alloys the casting and annealing technologies were adopted to fabricate the la08mg 02ni33co02si x (x = 0–02) electrode alloys the impacts of the addition of si and. Thermal analysis investigation of hydriding properties of nanocrystalline mg–ni- and mg–fe-based alloys prepared by high-energy ball milling - volume 16 issue 1 - l e a berlouis, e cabrera, e hall-barientos, p j hall, s b dodd, s morris , m a imam. The potential of la-mg-ni based alloys as a hydrogen storage material is promising because of their gravimetric hydrogen storage capacity, which can achieve a value ∼15 times higher than that of commercial lani5 in 2000, kadir et al  added another low cost element, ie calcium, into the la-mg-ni based alloys to. Xianda li mechanical alloying ti-ni based metallic compounds as negative electrode materials for ni-mh battery material chemistry université de technologie de discussion of ti-mg structure and its influence on hydrogen capacity mg-ni based , la-ni based , complex hydrides  etc.
The degradation mechanism of the la-mg-ni-based hydrogen storage electrode alloy la07mg03ni34mn01 during charge/ discharge cycling has been systematically studied using x-ray diffraction, x-ray photoelectron spectroscopy ( xps), auger electron spectroscopy (aes), scanning electron microscopy (sem),. Formation mechanism, phase structure and electrochemical properties of the la- mg-ni-based multiphase alloys by powder sintering lani5 and lamgni4 react with lamgni4 phase generating (la,mg)ni-3 and (la,mg)(2)ni-7 phases, and the mole ratio of precursors lani5/lamgni4 (x) affects the phase structures of alloys. Hindawi publishing corporation journal of chemistry volume 2013, article id 627582, 6 pages research article investigation on the structure and electrochemical properties of la-ce-mg-al-ni hydrogen storage alloy yuqing qiao,1,2 jianyi xi,2 minshou zhao,2 guangjie shao,2. Magnesium alloys are mixtures of magnesium with other metals (called an alloy), often aluminum, zinc, manganese, silicon, copper, rare earths and zirconium magnesium is the lightest structural metal magnesium alloys have a hexagonal lattice structure, which affects the fundamental properties of these alloys.
The hydriding kinetics of mg–ni based hydrogen storage alloys: a comparative study on chou model and jander model q luo, xh an, yb pan, x zhang, jy zhang, q li structures and properties of mg–la–ni ternary hydrogen storage alloys by microwave-assisted activation synthesis q li, y pan, h leng, k chou. La-mg-ni based alloys have a high hydrogen storage capacity, but their cycle stability is usually poor in this work, a series of composites were synthesized by mixing la-mg-ni based alloys with a commercial ab5 type alloy the aim was to investigate the effects of ab5 additions and ball milling treatment in.
Mg and the concentration ratios of other elements indicated the composition to be close to prmgni4 a dark phase was very heterogeneous in composition, attributed to the as-cast state of these alloys the phases identified by xrd analysis in the la07mg03al03mn04co 05ni38 alloy were: la(ni,co)5, laal( ni,co)4,. Al, b, c, ca, cr, cu, fe, h, la, mg, mn, ni, sc, si, sr, ti, v, zn, zr with data for the following phases phase list as well as providing excellent predictions for basic phase equilibria studies for most of the major types of aluminium alloy it has been highly successful in modelling complex non-equilibrium solidification. In this work, we studied the structural phase transformation and electrochemical characteristics of ab 4 -type la–mg–ni-based alloys through zoning annealing of la 078 mg 022 ni 390 polymorphic alloy the as-cast la 078 mg 022 ni 390 alloy contained two phases of lani 5 (508wt%) and (la,mg) 2 ni 7 (492wt%.
The structural and hydrogen storage properties in both gas-solid reaction and the electrochemical system were systematically studied on la07(mg03−xzrx)(ni 085co015)35 (x = 005, 01, 02, 03) alloys each tested alloy is composed of lani3 phase, lani5 phase and zrni3 phase with different phase.
Hydrogen storage by the anode alloy and on the amount of hydrogen reversely released from the alloy (amount of hydrogen storage) therefore, hydrogen storage alloys based on various new elements are being actively studied in particular la-mg-ni-type alloys are drawing much attention however, la-mg-ni- type alloys. Mgh2, mg2ni, mg60ni30la102xcox, cemg12z100%ni mg–lani5 1–3 suffer from poor hydrogen absorption and desorption rates at the ambient temperatures , hence inhibiting the application of these alloys in ni-mh therefore, a2b7 type la–mg–ni based hydrogen storage alloy has nowadays become the best choice.
One of homogenous alloys is amorphous nanocrystallisation of the amorphous lamg11ni alloy led to the formation of mg2ni/mg19la01ni and la18mg17ni1 nanocrystalline, which greatly improved the hydrogenation rate and lowered the temperature of hydrogen desorption another easily available. The cycle stability of la-mg-ni based alloys in a gas-solid reaction system was investigated in this work both partial substitutions of la and ni by ce and al, respectively, improved the cycle stability of la(065-x)cexca103mg132ni(9-y)al y alloys although the addition of al reduced the hydrogen storage. La–mg–ni based alloys have a high hydrogen storage capacity, but their cycle stability is usually poor in this work, a series of composites were synthesized by mixing la–mg–ni based alloys with a commercial ab5 type alloy the aim was to investigate the effects of ab5 additions and ball milling treatment. Results can develop the novel la-sc-ni-based hydrogen storage alloys by tuning their superlattice structures keywords: la-sc-ni-based hydrogen storage alloy, sc element substitution, microstructure, enthalpy change, electrochemical properties 1 introduction recently, ternary la-mg-ni.